We have to remember that the duration over which the force is applied makes a huge difference. The body can tolerate excesses of 10g momentarily, but over a period of seconds this would cause many people to "black out."
Tower of Terror sounds right, as >6 is fairly unusual on a roller coaster. Even sustained >5 can make people feel faint and/or momentarily black out, such as the pretzel loops on B&M flyers and the helices featured on some hypercoasters. I'm unable to find the G-force readings on the basic B&M flyer pretzel loop, but I'd be interested to see them, as Tatsu at SFMM makes me nearly black out.
I wonder if some older wooden rides wouldn't be in contention for negative. For example, Jack Rabbit at Kennywood hits a double dip so hard you can hear the upstops slam the track and the main wheels don't return for about a second on it.